Antifouling booster biocide extraction from marine sediments: a fast and simple method based on vortex-assisted matrix solid-phase extraction

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dc.citation.issue8
dc.citation.volumev. 25
dc.contributor.authorCaldas, Sergiane Souza
dc.contributor.authorSoares, Bruno Meira
dc.contributor.authorAbreu, Fiamma
dc.contributor.authorCastro, Ítalo Braga [UNIFESP]
dc.contributor.authorFillmann, Gilberto
dc.contributor.authorPrimel, Ednei Gilberto
dc.coverageHeidelberg
dc.date.accessioned2020-07-20T16:31:22Z
dc.date.available2020-07-20T16:31:22Z
dc.date.issued2018
dc.description.abstractThis paper reports the development of an analytical method employing vortex-assisted matrix solid-phase dispersion (MSPD) for the extraction of diuron, Irgarol 1051, TCMTB (2-thiocyanomethylthiobenzothiazole), DCOIT (4,5-dichloro-2-n-octyl-3-(2H)-isothiazolin-3-one), and dichlofluanid from sediment samples. Separation and determination were performed by liquid chromatography tandem-mass spectrometry. Important MSPD parameters, such as sample mass, mass of C18, and type and volume of extraction solvent, were investigated by response surface methodology. Quantitative recoveries were obtained with 2.0 g of sediment sample, 0.25 g of C18 as the solid support, and 10 mL of methanol as the extraction solvent. The MSPD method was suitable for the extraction and determination of antifouling biocides in sediment samples, with recoveries between 61 and 103% and a relative standard deviation lower than 19%. Limits of quantification between 0.5 and 5 ng g(-1) were obtained. Vortex-assisted MPSD was shown to be fast and easy to use, with the advantages of low cost and reduced solvent consumption compared to the commonly employed techniques for the extraction of booster biocides from sediment samples. Finally, the developed method was applied to real samples. Results revealed that the developed extraction method is effective and simple, thus allowing the determination of biocides in sediment samples.en
dc.description.affiliationUniv Fed Rio Grande, Lab Anal Compostos Organ & Metais, Escola Quim & Alimentos, Av Italia,Km 8 S-N, BR-96201900 Rio Grande, RS, Brazil
dc.description.affiliationUniv Fed Rio Grande, Inst Oceanog, Lab Microcontaminantes Organ & Ecotoxicol Aquat, Av Italia,Km 8 S-N, BR-96201900 Rio Grande, RS, Brazil
dc.description.affiliationUniv Fed Sao Paulo, Inst Mar, Labo Ecotoxicol & Contaminacao Marinha, Av Almirante Saldanha da Gama 89, BR-11030400 Santos, SP, Brazil
dc.description.affiliationUnifespUniv Fed Sao Paulo, Inst Mar, Labo Ecotoxicol & Contaminacao Marinha, Av Almirante Saldanha da Gama 89, BR-11030400 Santos, SP, Brazil
dc.description.sourceWeb of Science
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado do Rio Grande do Sul (FAPERGS)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipFinanciadora de Estudos e Projetos (FINEP)
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.description.sponsorshipIDCNPq: DT 311694/2016-0
dc.format.extent7553-7565
dc.identifierhttps://dx.doi.org/10.1007/s11356-017-0942-x
dc.identifier.citationEnvironmental Science And Pollution Research. Heidelberg, v. 25, n. 8, p. 7553-7565, 2018.
dc.identifier.doi10.1007/s11356-017-0942-x
dc.identifier.issn0944-1344
dc.identifier.urihttps://repositorio.unifesp.br/handle/11600/55911
dc.identifier.wosWOS:000427398200043
dc.language.isoeng
dc.publisherSpringer Heidelberg
dc.relation.ispartofEnvironmental Science And Pollution Research
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectVortex-assisted matrix solid-phase dispersionen
dc.subjectBiocidesen
dc.subjectLiquid chromatographyen
dc.subjectSedimenten
dc.titleAntifouling booster biocide extraction from marine sediments: a fast and simple method based on vortex-assisted matrix solid-phase extractionen
dc.typeinfo:eu-repo/semantics/article
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