Hydrogen storage properties of 2Mg-Fe mixtures processed by hot extrusion at different temperatures

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dc.citation.issue16
dc.citation.volume42
dc.contributor.authorde Lima Andreani, G. F. [UNIFESP]
dc.contributor.authorMiglioli, M. M.
dc.contributor.authorTriques, M. R. M.
dc.contributor.authorRoche, V.
dc.contributor.authorKiminami, C. S.
dc.contributor.authorBotta, W. J.
dc.contributor.authorJorge, A. M., Jr.
dc.coverageOxford
dc.date.accessioned2020-07-17T14:02:16Z
dc.date.available2020-07-17T14:02:16Z
dc.date.issued2017
dc.description.abstract2Mg-Fe mixtures produced by high-energy ball milling were consolidated into bulk form by hot extrusion at different processing temperatures (573 K (300 degrees C), 623 K (350 degrees C) and 673 K (400 degrees C)), aiming to evaluate their influence on the structure and microstructure of bulk materials and their consequent influence on the hydrogen sorption properties. In spite being in the nanosize range, the highest the processing temperature, the larger the grain sizes. However, the nanometric grain size remained after any hot extrusion condition, as estimated by Rietveld refinement. The pinning effect of Fe on Mg grain boundaries explained this effect. In the first absorption (activation), powders showed a hydrogen storage capacity of similar to 4.53 wt%, while the extruded samples (bulk materials) reached almost the same capacity during the period of hydrogenation (similar to 94% of the maximum hydrogen storage capacity for Mg2FeH6 - 5.5 wt%). The smallest crystallite sizes and highest surface area for hydrogenation explain the good performance of powders. However, when comparing only extruded samples, it was observed that the highest capacity and the lowest incubation times were mainly related to grain sizes and to the favorable texture along (002) plane of alpha Mg. The desorption temperature of bulk materials was very similar to that of powders, which is good considering the lower surface area of bulk materials. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.en
dc.description.affiliationUniv Fed Sao Paulo, Dept Sci & Technol, Talim St 330, BR-12231280 Sao Jose Dos Campos, SP, Brazil
dc.description.affiliationUniv Fed Sao Carlos, Dept Mat Engn, Via Washington Luiz Km 235, Sao Carlos, SP, Brazil
dc.description.affiliationUniv Grenoble Alpes, LEPMI, F-38000 Grenoble, France
dc.description.affiliationCNRS, LePMI, F-38000 Grenoble, France
dc.description.affiliationUniv Grenoble Alpes, SIMAP, F-38000 Grenoble, France
dc.description.affiliationCNRS, SIMaP, F-38000 Grenoble, France
dc.description.affiliationUnifespUniv Fed Sao Paulo, Dept Sci & Technol, Talim St 330, BR-12231280 Sao Jose Dos Campos, SP, Brazil
dc.description.sourceWeb of Science
dc.description.sponsorshipBrazilian agency FAPESP
dc.description.sponsorshipBrazilian agency CNPq
dc.description.sponsorshipIDFAPESP: 2013/05987-8
dc.description.sponsorshipIDFAPESP: 2014/21237-1
dc.description.sponsorshipIDCNPq: 460471/2014-7
dc.format.extent11493-11500
dc.identifierhttp://dx.doi.org/10.1016/j.ijhydene.2017.02.213
dc.identifier.citationInternational Journal Of Hydrogen Energy. Oxford, v. 42, n. 16, p. 11493-11500, 2017.
dc.identifier.doi10.1016/j.ijhydene.2017.02.213
dc.identifier.issn0360-3199
dc.identifier.urihttps://repositorio.unifesp.br/handle/11600/54711
dc.identifier.wosWOS:000403381400074
dc.language.isoeng
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofInternational Journal Of Hydrogen Energy
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.subjectHydrogen storageen
dc.subject2Mg-Feen
dc.subjectMechanical alloyingen
dc.subjectHot extrusionen
dc.titleHydrogen storage properties of 2Mg-Fe mixtures processed by hot extrusion at different temperaturesen
dc.typeinfo:eu-repo/semantics/article
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