Langmuir and Langmuir-Blodgett films of Cl-PPV mixed with stearic acid: implication of the morphology on the surface and spectroscopy properties

dc.contributor.authorSakai, Andrei [UNIFESP]
dc.contributor.authorPeres, Laura O. [UNIFESP]
dc.contributor.authorCaseli, Luciano [UNIFESP]
dc.contributor.institutionUniversidade Federal de São Paulo (UNIFESP)
dc.date.accessioned2016-01-24T14:40:08Z
dc.date.available2016-01-24T14:40:08Z
dc.date.issued2015-03-01
dc.description.abstractThe molecular architecture of polymeric films can be changed in order to obtain enhanced properties for the fabrication of optoelectronic devices. in this paper, poly(2-chloro-p-phenylenevinylene) was spread on the air-water interface and mixed with stearic acid in order to form stable Langmuir monolayers. These films were transferred from the air-water interface to solid supports as Langmuir-Blodgett (LB) films. the influence of Cl in the polymer chain was investigated with measurements of surface pressure, polarization modulation infrared reflection-absorption spectroscopy (PM-IRRAS), Brewster angle microscopy (BAM), atomic force microscopy (AFM), and fluorescence spectroscopy. the immobilization of this polymer on solid supports as LB films provided a high control of its morphological and luminescence properties, which may be useful tomanipulate structures at the molecular level to be applied as optoelectronic devices.en
dc.description.affiliationUniversidade Federal de São Paulo, Inst Environm Chem & Pharmaceut Sci, Diadema, SP, Brazil
dc.description.affiliationUnifespUniversidade Federal de São Paulo, Inst Environm Chem & Pharmaceut Sci, Diadema, SP, Brazil
dc.description.sourceWeb of Science
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipnBioNet: Films and Sensors
dc.description.sponsorshipINEO (National Institute of Science and Technology for Organic Electronics)
dc.description.sponsorshipIDFAPESP: 2013/10213-1
dc.format.extent883-890
dc.identifierhttp://dx.doi.org/10.1007/s00396-014-3477-4
dc.identifier.citationColloid and Polymer Science. New York: Springer, v. 293, n. 3, p. 883-890, 2015.
dc.identifier.doi10.1007/s00396-014-3477-4
dc.identifier.issn0303-402X
dc.identifier.urihttp://repositorio.unifesp.br/handle/11600/38811
dc.identifier.wosWOS:000350367200021
dc.language.isoeng
dc.publisherSpringer
dc.relation.ispartofColloid and Polymer Science
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.rights.licensehttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dc.subjectPPVen
dc.subjectStearic aciden
dc.subjectMonolayeren
dc.subjectAir-water interfaceen
dc.subjectLangmuir-Blodgett filmsen
dc.titleLangmuir and Langmuir-Blodgett films of Cl-PPV mixed with stearic acid: implication of the morphology on the surface and spectroscopy propertiesen
dc.typeinfo:eu-repo/semantics/article
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