Green Extraction Approaches for Carotenoids and Esters: Characterization of Native Composition from Orange Peel

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dc.citation.issue12pt_BR
dc.citation.volume8pt_BR
dc.contributor.authorMurador, Daniella Carisa [UNIFESP]
dc.contributor.authorSalafia, Fabio
dc.contributor.authorZoccali, Mariosimone
dc.contributor.authorMartins, Paula Larangeira Garcia
dc.contributor.authorFerreira, Antônio Gilberto
dc.contributor.authorDugo, Paola
dc.contributor.authorMondello, Luigi
dc.contributor.authorRosso, Veridiana Vera de [UNIFESP]
dc.contributor.authorGiuffrida, Daniele
dc.contributor.institutionUniversidade Federal de São Paulo (UNIFESP)
dc.coverage.spatialBaselpt_BR
dc.date.accessioned2020-05-11T18:36:58Z
dc.date.available2020-05-11T18:36:58Z
dc.date.issued2019
dc.description.abstractAbstract: Orange peel is a by-product produced in large amounts that acts as a source of natural pigments such as carotenoids. Xanthophylls, the main carotenoid class found in citrus fruit, can be present in its free form or esterified with fatty acids, forming esters. This esterification modifies the compound’s chemical properties, affecting their bioavailability in the human body, and making it important to characterize the native carotenoid composition of food matrices. We aimed to evaluate the non-saponified carotenoid extracts of orange peel (cv. Pera) obtained using alternative green approaches: extraction with ionic liquid (IL), analyzed by high performance liquid chromatography coupled to a diode array detector with atmospheric pressure chemical ionization and mass spectrometry HPLC-DAD-APCI-MS, and supercritical fluid extraction (SFE), followed by supercritical fluid chromatography with atmospheric pressure chemical ionization and triple quadrupole mass spectrometry detection (SFC-APCI/QqQ/MS) in an online system. Both alternative green methods were successfully applied, allowing the total identification of five free carotenoids, one apocarotenoid, seven monoesters, and 11 diesters in the extract obtained with IL and analyzed by HPLC-DAD-APCI-MS, and nine free carotenoids, six carotenoids esters, 19 apocarotenoids, and eight apo-esters with the SFE-SFC-APCI/QqQ/MS approach, including several free apocarotenoids and apocarotenoid esters identified for the first time in oranges, and particularly in the Pera variety, which could be used as a fruit authenticity parameter.
dc.description.affiliationBioscience Department, Universidade Federal de São Paulo, Rua Silva Jardin 136, 11015-020 Santos, Brazil
dc.description.affiliationDepartment of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Polo Annunziata, Viale Annunziata, 98168 Messina, Italy
dc.description.affiliationDepartment of Mathematical and Computer Science, Physical Sciences and Earth Sciences, University of Messina, 98168 Messina, Italy
dc.description.affiliationFederal Institute of São Paulo, Av. Clara Gianotti de Souza 5180, 11900-000 Registro, Brazil
dc.description.affiliationChemistry Department, Federal University of São Carlos, Rodovia Washington Luíz, Km 235, 13565-905 São Carlos, Brazil
dc.description.affiliationChromaleont s.r.l., c/o Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, 98166 Messina, Italy
dc.description.affiliationBeSep s.r.l., c/o Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, 98166 Messina, Italy
dc.description.affiliationUnit of Food Science and Nutrition, Department of Medicine, University Campus Bio-Medico of Rome, 00128 Rome, Italy
dc.description.affiliationDepartment of Biomedical, Dental, Morphological and Functional Imaging Sciences, University of Messina, Via Consolare Valeria, 98125 Messina, Italy
dc.description.affiliationUnifespBioscience Department, Universidade Federal de São Paulo, Rua Silva Jardin 136, 11015-020 Santos, Brazil
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)pt_BR
dc.description.sponsorshipIDFAPESP: 2015/26789-5pt
dc.description.sponsorshipIDFAPESP: 2016/18910-1pt
dc.description.sponsorshipIDFAPESP: 2017/20861-1pt
dc.description.sponsorshipIDFAPESP: 2019/25303-2pt
dc.identifierhttps://doi.org/10.3390/antiox8120613pt_BR
dc.identifier.citationMurador DC, Salafia F, Zoccali M, Martins PLG, Ferreira AG, Dugo P, et al. Green Extraction Approaches for Carotenoids and Esters: Characterization of Native Composition from Orange Peel. Antioxidants [Internet]. MDPI AG; 2019 Dec 3;8(12):613. Available from: http://dx.doi.org/10.3390/antiox8120613pt_BR
dc.identifier.doi10.3390/antiox8120613pt_BR
dc.identifier.fileMurador - Antioxidants.pdf
dc.identifier.issn2076-3921pt_BR
dc.identifier.urihttps://repositorio.unifesp.br/handle/11600/53338
dc.languageengpt_BR
dc.publisherMDPIpt_BR
dc.relation.ispartofAntioxidantspt_BR
dc.rightsinfo:eu-repo/semantics/openAccesspt_BR
dc.subjectCitruspt_BR
dc.subjectXanthophylls
dc.subjectEsterification
dc.subjectFatty acids
dc.subjectApocarotenoids
dc.subjectIonic liquid
dc.subject[C4mim]Cl
dc.subjectSupercritical fluid
dc.titleGreen Extraction Approaches for Carotenoids and Esters: Characterization of Native Composition from Orange Peelpt_BR
dc.typeinfo:eu-repo/semantics/articlept_BR
unifesp.campusInstituto de Saúde e Sociedade (ISS)pt_BR
unifesp.departamentoBiociênciaspt_BR
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