Activation energy for the reverse eutectoid reaction in hypo-eutectoid Cu-Al alloys

dc.contributor.authorAdorno, A. T.
dc.contributor.authorCarvalho, T. M.
dc.contributor.authorMagdalena, A. G.
dc.contributor.authorSantos, C. M. A. dos
dc.contributor.authorSilva, R. A. G. [UNIFESP]
dc.contributor.institutionUNESP
dc.contributor.institutionUniversidade Federal de São Paulo (UNIFESP)
dc.date.accessioned2016-01-24T14:26:58Z
dc.date.available2016-01-24T14:26:58Z
dc.date.issued2012-03-10
dc.description.abstractThe values of the activation energy for the reverse eutectoid reaction (alpha + gamma(1)) -> beta in the Cu-9 wt.%Al, Cu-10 wt.%Al and Cu-11 wt.%Al alloys were obtained using nonisothermal methods and considering two different reaction paths, one starting from annealed alloys and other from quenched alloys. the results showed that the activation energy for the reaction changes with Al concentration and strongly depends on the reaction path. the conversion dependence of the activation energy indicates a complex process comprising consecutive reactions which may be related with the dissolution of the pearlitic phase prior to the beta phase formation. (C) 2012 Elsevier B.V. All rights reserved.en
dc.description.affiliationUNESP, Dept Quim Fis, Inst Quim, BR-14801970 Araraquara, SP, Brazil
dc.description.affiliationUNIFESP, Dept Ciencias Exatas & Terra, BR-09972270 Diadema, SP, Brazil
dc.description.affiliationUnifespUNIFESP, Dept Ciencias Exatas & Terra, BR-09972270 Diadema, SP, Brazil
dc.description.sourceWeb of Science
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.format.extent35-41
dc.identifierhttp://dx.doi.org/10.1016/j.tca.2011.12.027
dc.identifier.citationThermochimica Acta. Amsterdam: Elsevier B.V., v. 531, p. 35-41, 2012.
dc.identifier.doi10.1016/j.tca.2011.12.027
dc.identifier.issn0040-6031
dc.identifier.urihttp://repositorio.unifesp.br/handle/11600/34708
dc.identifier.wosWOS:000301309700006
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofThermochimica Acta
dc.rightsinfo:eu-repo/semantics/restrictedAccess
dc.rights.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.subjectNonisothermal kineticsen
dc.subjectEutectoid reactionen
dc.subjectCu-Al alloysen
dc.titleActivation energy for the reverse eutectoid reaction in hypo-eutectoid Cu-Al alloysen
dc.typeinfo:eu-repo/semantics/article
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