Dammarane Triterpenoids from Carnauba, Copernicia prunifera (Miller) H. E. Moore (Arecaceae), Wax

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Data
2017
Autores
de Almeida, Buana C.
Araujo, Bruno Q.
Barros, Elcio D. S.
Freitas, Samya D. L.
Maciel, Dayany S. A. [UNIFESP]
Ferreira, Ari J. S. [UNIFESP]
Guadagnin, Rafael C. [UNIFESP]
Vieira Junior, Gerardo M.
Lago, Joao H. G. [UNIFESP]
Chaves, Mariana H.
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Resumo
Phytochemical investigation from carnauba (Copernicia prunifera) wax led to the identification of sixteen dammarane-type triterpenes, including thirteen new characterized as: (24R*)-methyldammara-20,25-dien-3 alpha-ol and a mixture of alkyl (24R*)-methyldammar-25-en- 20-ol-3 beta-carboxylates, together with three previously described triterpenes: carnaubadiol, (24R*)-methyldammara-20,25-dien-3 beta-ol and (24R*)-24-methyldammara-20,25-dien-3-one. Moreover, four fatty alcohols (eicosanol, docosanol, tetracosanol and hexacosanol) as well as four sterols (cholesterol, campesterol, stigmasterol, and sitosterol) were also obtained. These compounds were isolated using classical chromatographic methods and their structures were determined by spectroscopic and chemical methods.
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Journal Of The Brazilian Chemical Society. Sao Paulo, v. 28, n. 8, p. 1371-1376, 2017.
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