Abatement of the inhibitory effect of chloride anions on the photo-Fenton process
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Data
2007-12-15
Autores
Machulek, Amilcar
Moraes, Jose E. F. [UNIFESP]
Vautier-Giongo, Carolina [UNIFESP]
Silverio, Cristina A.
Friedrich, Leidi C.
Nascimento, Claudio A. O.
Gonzalez, Monica C.
Quina, Frank H.
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The inhibition of the photo-Fenton (Fe2+/Fe3+, H2O2, UV light) degradation of synthetic phenol wastewater solutions by chloride ions is shown to affect primarily the photochemical step of the process, having only a slight effect on the thermal or Fenton step. Kinetic studies of the reactions of oxoiron (IV) (FeO2+) with phenol indicate that, if FeO2+ is formed in the photo-Fenton degradation, its role is probably minor. Finally, it is shown that, for both a synthetic phenol wastewater and an aqueous extract of Brazilian gasoline, the inhibition of the photo-Fenton degradation of the organic material in the presence of chloride ion can be circumvented by maintaining the pH of the medium at or slightly above 3 throughout the process, even in the presence of significant amounts of added chloride ion (0.5 M).
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Environmental Science & Technology. Washington: Amer Chemical Soc, v. 41, n. 24, p. 8459-8463, 2007.