Dissolution and doping of polyaniline emeraldine base in imidazolium ionic liquids investigated by spectroscopic techniques

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Data
2007-03-01
Autores
Rodrigues, Fabio
Nascimento, Gustavo M. do
Santos, Paulo S.
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Polyaniline is a model molecular system in the study of conductive polymers. Ionic liquids, on the other hand, are becoming more and more a very convenient alternative for conventional organic solvents. the dissolution of polyaniline-emeraldine base (PANI-EB) in imidazolium ILs leads to its doping, as indicated by optical and resonance Raman spectroscopies. in this study, it is proposed that the interaction of PANI-EB and imidazolium ILs involves the specific interaction of the quinoid moiety of the former with the imidazolium ring of the latter, an interpretation that is also based on N K-edge XANES measurements of neat PANI-EB, neat ILs, and of their solutions.
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Macromolecular Rapid Communications. Weinheim: Wiley-v C H Verlag Gmbh, v. 28, n. 5, p. 666-669, 2007.