Browsing by Subject "benzyne chemistry"

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    • Convergent Total Synthesis of (+/-)-Apomorphine via Benzyne Chemistry: Insights into the Mechanisms Involved in the Key Step 

      Muraca, Ana Carolina A. [UNIFESP]; Perecim, Givago P. [UNIFESP]; Rodrigues, Alessandro [UNIFESP]; Raminelli, Cristiano [UNIFESP] (Georg Thieme Verlag Kg, 2017)
      Convergent total synthesis of (+/-)-apomorphine hydrochloride was accomplished by an approach that employs in the key step a sequence of transformations involving a [4+2]-cycloaddition reaction followed by a hydrogen ...

    • Synthesis of Silylbiaryl Triflates by Chemoselective Suzuki Reaction 

      Moreira, Barbara V. [UNIFESP]; Muraca, Ana Carolina A. [UNIFESP]; Raminelli, Cristiano [UNIFESP] (Georg Thieme Verlag Kg, 2017)
      A modular approach for the synthesis of functionalized silylbiaryl triflates has been developed. Iodinated silylaryl triflates were prepared via a gram-scale diiodination reaction, followed by a one-flask transformation, ...