Please use this identifier to cite or link to this item: https://repositorio.unifesp.br/handle/11600/37627
Title: Laser ablation inductively coupled plasma optical emission spectrometry for analysis of pellets of plant materials
Authors: Gomes, Marcos S.
Schenk, Emily R.
Santos, Dario [UNIFESP]
Krug, Francisco Jose
Almirall, Jose R.
Universidade Federal de São Carlos (UFSCar)
Universidade de São Paulo (USP)
Florida Int Univ
Universidade Federal de São Paulo (UNIFESP)
Keywords: LA-ICP OES
Laser ablation
Optical emission spectroscopy
Plant material
Macronutrient
Micronutrient
Issue Date: 1-Apr-2014
Publisher: Elsevier B.V.
Citation: Spectrochimica Acta Part B-atomic Spectroscopy. Oxford: Pergamon-Elsevier B.V., v. 94-95, p. 27-33, 2014.
Abstract: An evaluation of laser ablation inductively coupled plasma optical emission spectroscopy (LAICP OES) for the direct analysis of pelleted plant material is reported. Ground leaves of orange citrus, soy and sugarcane were comminuted using a high-speed ball mill, pressed into pellets and sampled directly with laser ablation and analyzed by ICP OES. the limits of detection (LODs) for the method ranged from as low as 0.1 mg kg(-1) for Zn to as high as 94 mg kg(-1) for K but were generally below 6 mg kg(-1) for most of the elements of interest. A certified reference material consisting of a similar matrix (NIST SRM 1547 peach leaves) was used to check the accuracy of the calibration and the reported method resulted in an average bias of similar to 5% for all the elements of interest. the precision for the reported method ranged from as low as 4% relative standard deviation (RSD) for Mn to as high as 17% RSD for Zn but averaged similar to 6.5% RSD for all the elements (n = 10). the proposed method was tested for the determination of Ca, Mg, P, K, Fe, Mn, Zn and B, and the results were in good agreement with those obtained for the corresponding acid digests by ICP-OES, no differences being observed by applying a paired t-test at the 95% confidence level. the reported direct solid sampling method provides a fast alternative to acid digestion that results in similar and appropriate analytical figures of merit with regard to sensitivity, accuracy and precision for plant material analysis. (C) 2014 Elsevier B.V. All rights reserved.
URI: http://repositorio.unifesp.br/handle/11600/37627
ISSN: 0584-8547
Other Identifiers: http://dx.doi.org/10.1016/j.sab.2014.03.005
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