Formation of Composite Polyaniline and Graphene Oxide by Physical Mixture Method

Formation of Composite Polyaniline and Graphene Oxide by Physical Mixture Method

Author Vargas, Ludmila Resende Google Scholar
Poli, Anne Karoline Google Scholar
Lazzarini Dutra, Rita de Cassia Google Scholar
Souza, Camila Brito de Autor UNIFESP Google Scholar
Baldan, Mauricio Ribeiro Google Scholar
Goncalves, Emerson Sarmento Google Scholar
Abstract The development of polyaniline and graphene oxide composites aims to join the unique properties of each material for aerospace applications. The present paper demonstrates an easy and quick method, compared to the ones found in the literature, to obtain a composite made with polyaniline doped with dodecylbenzenesulfonic acid, a combination commonly called polyaniline, and graphene oxide. Nowadays, the most common studied methods are electrochemistry and in situ chemical polymerization. Differently from these methods, the films were obtained by a physical mixture of equimolar suspension of graphene oxide (4 mg/mL) with 3 concentrations of polyaniline powder: 25

50 and 75%, being compared to pure graphene oxide and polyaniline. The morphology and structure behavior of all the films were studied, besides the bonding nature between both materials. The films were analyzed by scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, and differential scanning calorimetry. The apparent interaction between graphene oxide corrugated sheets and polyaniline grains was verified by scanning electron microscopy images. It can be noticed, as the concentration of polyaniline increases, that more polymer was entrapped. To prove the formation of polyaniline/graphene oxide composite, X-ray diffraction and Fourier transform infrared spectroscopy techniques demonstrated the changes on graphene oxide crystallographic plans and on the chemical bonding between polyaniline and graphene oxide, suggesting an interaction between polyaniline and graphene oxide, especially in the composite with 50% polyaniline/50% graphene oxide. Differential scanning calorimetry was used to highlight this effect through the increase in thermal stability. The method of physical mixture was efficient to obtain the polyaniline/graphene oxide composites.
Keywords Graphene oxide
Polyaniline
Structure
Morphology
FT-IR
DSC
xmlui.dri2xhtml.METS-1.0.item-coverage Sao Paulo
Language English
Sponsor Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
Instituto Tecnológico de Aeronáutica
Divisão de Química of the Instituto de Aeronáutica e Espaço
Date 2017
Published in Journal Of Aerospace Technology And Management. Sao Paulo, v. 9, n. 1, p. 29-38, 2017.
ISSN 1984-9648 (Sherpa/Romeo, impact factor)
Publisher Inst Aeronautica & Espaco-Iae
Extent 29-38
Origin http://dx.doi.org/10.5028/jatm.v9i1.697
Access rights Open access Open Access
Type Article
Web of Science ID WOS:000395632200003
URI https://repositorio.unifesp.br/handle/11600/56394

Show full item record




File

Name: WOS000395632200003.pdf
Size: 2.247Mb
Format: PDF
Description:
Open file

This item appears in the following Collection(s)

Search


Browse

Statistics

My Account