Green Extraction Approaches for Carotenoids and Esters: Characterization of Native Composition from Orange Peel

Show simple item record

dc.contributor.author Murador, Daniella C. [UNIFESP]
dc.contributor.author Salafia, Fabio
dc.contributor.author Zoccali, Mariosimone
dc.contributor.author Martins, Paula L. G.
dc.contributor.author Ferreira, Antônio G.
dc.contributor.author Dugo, Paola
dc.contributor.author Mondello, Luigi
dc.contributor.author Rosso, Veridiana V. de [UNIFESP]
dc.contributor.author Giuffrida, Daniele
dc.coverage.spatial Basel pt_BR
dc.date.accessioned 2020-05-11T18:36:58Z
dc.date.available 2020-05-11T18:36:58Z
dc.date.issued 2019
dc.identifier https://doi.org/10.3390/antiox8120613 pt_BR
dc.identifier.citation Murador DC, Salafia F, Zoccali M, Martins PLG, Ferreira AG, Dugo P, et al. Green Extraction Approaches for Carotenoids and Esters: Characterization of Native Composition from Orange Peel. Antioxidants [Internet]. MDPI AG; 2019 Dec 3;8(12):613. Available from: http://dx.doi.org/10.3390/antiox8120613 pt_BR
dc.identifier.issn 2076-3921 pt_BR
dc.identifier.uri https://repositorio.unifesp.br/handle/11600/53338
dc.description.abstract Abstract: Orange peel is a by-product produced in large amounts that acts as a source of natural pigments such as carotenoids. Xanthophylls, the main carotenoid class found in citrus fruit, can be present in its free form or esterified with fatty acids, forming esters. This esterification modifies the compound’s chemical properties, affecting their bioavailability in the human body, and making it important to characterize the native carotenoid composition of food matrices. We aimed to evaluate the non-saponified carotenoid extracts of orange peel (cv. Pera) obtained using alternative green approaches: extraction with ionic liquid (IL), analyzed by high performance liquid chromatography coupled to a diode array detector with atmospheric pressure chemical ionization and mass spectrometry HPLC-DAD-APCI-MS, and supercritical fluid extraction (SFE), followed by supercritical fluid chromatography with atmospheric pressure chemical ionization and triple quadrupole mass spectrometry detection (SFC-APCI/QqQ/MS) in an online system. Both alternative green methods were successfully applied, allowing the total identification of five free carotenoids, one apocarotenoid, seven monoesters, and 11 diesters in the extract obtained with IL and analyzed by HPLC-DAD-APCI-MS, and nine free carotenoids, six carotenoids esters, 19 apocarotenoids, and eight apo-esters with the SFE-SFC-APCI/QqQ/MS approach, including several free apocarotenoids and apocarotenoid esters identified for the first time in oranges, and particularly in the Pera variety, which could be used as a fruit authenticity parameter.
dc.description.sponsorship Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) pt_BR
dc.language eng pt_BR
dc.publisher MDPI pt_BR
dc.relation.ispartof Antioxidants pt_BR
dc.rights Acesso aberto pt_BR
dc.subject citrus pt_BR
dc.subject xanthophylls
dc.subject esterification
dc.subject fatty acids
dc.subject apocarotenoids
dc.subject ionic liquid
dc.subject [C4mim]Cl
dc.subject supercritical fluid
dc.title Green Extraction Approaches for Carotenoids and Esters: Characterization of Native Composition from Orange Peel pt_BR
dc.type Artigo pt_BR
dc.description.affiliation Bioscience Department, Universidade Federal de São Paulo, Rua Silva Jardin 136, 11015-020 Santos, Brazil
dc.description.affiliation Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Polo Annunziata, Viale Annunziata, 98168 Messina, Italy
dc.description.affiliation Department of Mathematical and Computer Science, Physical Sciences and Earth Sciences, University of Messina, 98168 Messina, Italy
dc.description.affiliation Federal Institute of São Paulo, Av. Clara Gianotti de Souza 5180, 11900-000 Registro, Brazil
dc.description.affiliation Chemistry Department, Federal University of São Carlos, Rodovia Washington Luíz, Km 235, 13565-905 São Carlos, Brazil
dc.description.affiliation Chromaleont s.r.l., c/o Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, 98166 Messina, Italy
dc.description.affiliation BeSep s.r.l., c/o Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, 98166 Messina, Italy
dc.description.affiliation Unit of Food Science and Nutrition, Department of Medicine, University Campus Bio-Medico of Rome, 00128 Rome, Italy
dc.description.affiliation Department of Biomedical, Dental, Morphological and Functional Imaging Sciences, University of Messina, Via Consolare Valeria, 98125 Messina, Italy
dc.description.affiliationUnifesp Bioscience Department, Universidade Federal de São Paulo, Rua Silva Jardin 136, 11015-020 Santos, Brazil
dc.description.sponsorshipID FAPESP: 2015/26789-5
dc.description.sponsorshipID FAPESP: 2016/18910-1
dc.description.sponsorshipID FAPESP: 2017/20861-1
dc.description.sponsorshipID FAPESP: 2019/25303-2
dc.identifier.file Murador - Antioxidants.pdf
dc.identifier.doi 10.3390/antiox8120613 pt_BR
unifesp.campus Instituto de Saúde e Sociedade (ISS) pt_BR
dc.citation.volume 8 pt_BR
dc.citation.issue 12 pt_BR
unifesp.departamento Biociências pt_BR



File

Name: Murador - Antioxidants.pdf
Size: 1.193Mb
Format: PDF
Description:
Open file

This item appears in the following Collection(s)

Show simple item record

Search


Browse

Statistics

My Account