Sulfonated poly(ether imide)/aluminium nanocomposites for hydrogen storage

Sulfonated poly(ether imide)/aluminium nanocomposites for hydrogen storage

Author Beatrice, Cesar A. G. Google Scholar
Oliveira, Amanda D. Google Scholar
Passador, Fabio R. Autor UNIFESP Google Scholar
Pessan, Luiz A. Google Scholar
Abstract Mobility is a socioeconomic reality that increases every year and it should be safe, economic and reasonably clean. Little energy needs to be expended to overcome potential energy changes, but a great deal is lost through friction and low-efficiency energy conversion. Hydrogen would be ideal as a synthetic fuel because it is lightweight, highly abundant and its oxidation product (water) is environmentally benign, but storage remains a problem. The clean way to produce hydrogen from water is to use sunlight in combination with photovoltaic cells and water electrolysis, although other forms of primary energy and other water-splitting processes are generally used. The chemical energy per mass of hydrogen is at least three times larger than that of other chemical fuels. Hydrogen adsorbs at solid surfaces depending on the applied pressure and temperature. The variation of attractive surface forces as a function of distance from the surface decides whether van der Waals-type weak physisorption of molecular hydrogen occurs, or whether dissociation and chemisorption of atomic hydrogen takes place. For storage purposes in mobile applications, the adsorption of hydrogen has been studied mainly on carbon species, but light and reasonably cheap materials of high surface area should prove to be attractive as well. In this work nanocomposites with sulfonated poly(ether imide) and faujasite-type zeolite doped with aluminium were prepared using different amounts of nanoparticles. Their morphology and hydrogen storage capacity were evaluated. Hydrogen sorption tests were carried out and there was a significant increase in the amount of hydrogen to the composite relative to the one without aluminum. Considering previous results it is scientifically interesting to continue research on the interaction of hydrogen with different and well-characterized polymer-based nanocomposites.
Language English
Date 2016
Published in Proceedings Of The Regional Conference Graz 2015 - Polymer Processing Society Pps: Conference Papers. Melville, v. 1779, p. UNSP 040004, 2016.
ISSN 0094-243X (Sherpa/Romeo, impact factor)
Publisher Karger
Extent UNSP 040004
Origin https://doi.org/10.1063/1.4965495
Access rights Open access Open Access
Type Conference paper
Web of Science ID WOS:000389510600044
URI http://repositorio.unifesp.br/handle/11600/49333

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