In situ generation of n-butanethiol and its reaction with electron-deficient olefines

In situ generation of n-butanethiol and its reaction with electron-deficient olefines

Author Gariani, Rogerio A. Google Scholar
Dos Santos, Alcindo A. Autor UNIFESP Google Scholar
Comasseto, Joao V. Google Scholar
Institution Universidade de São Paulo (USP)
Universidade Federal de São Paulo (UNIFESP)
Abstract n-Butanethiol is generated in situ by sequential addition of n-butyllithium and water to elemental sulfur. the n-butanethiol formed was reacted with electron-deficient olefines to give Michael-type addition products in good yields. the method avoids the manipulation of the bad-smelling n-butanethiol.
Keywords Michael addition
thiols
alpha,beta-unsaturated carbonyl compound
Language English
Date 2008-01-01
Published in Synthetic Communications. Philadelphia: Taylor & Francis Inc, v. 38, n. 5, p. 789-795, 2008.
ISSN 0039-7911 (Sherpa/Romeo, impact factor)
Publisher Taylor & Francis Inc
Extent 789-795
Origin http://dx.doi.org/10.1080/00397910701820897
Access rights Closed access
Type Article
Web of Science ID WOS:000253334800015
URI http://repositorio.unifesp.br/handle/11600/30309

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